双(1,5-环辛二烯)四氟硼酸铑(I) CAS 35138-22-8

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 35138-22-8 BIS(1,5-CYCLOOCTADIEN)RHODIUM(I) TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIENE)RHODIUM TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE;BIS(CYCLOOCTA-1,5-DIEN)RHODIUM(I)-TETRAFLUOROBORATE;BIS(CYCLOOCTA-1,5-DIENE)RHODIUM(I) TETRAFLUOROBORATE;RHODIUM(I) TETRAFLUOROBORATE 1,5-CYCLOOCTADIENE COMPLEX SC10102

纯度 97%+现货药物标准品
CAS 号35138-22-8
分子式2*C8H12 Rh BF4
分子量N/A g/mol
分类药物标准品 / 原料药标准品
库存状态现货

化学结构式 Structure

双(1,5-环辛二烯)四氟硼酸铑(I) Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 35138-22-8 BIS(1,5-CYCLOOCTADIEN)RHODIUM(I) TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIENE)RHODIUM TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE;BIS(CYCLOOCTA-1,5-DIEN)RHODIUM(I)-TETRAFLUOROBORATE;BIS(CYCLOOCTA-1,5-DIENE)RHODIUM(I) TETRAFLUOROBORATE;RHODIUM(I) TETRAFLUOROBORATE 1,5-CYCLOOCTADIENE COMPLEX SC10102 CAS 35138-22-8 结构式 Chemical Structure

产品介绍 Description

双(1,5-环辛二烯)四氟硼酸铑(I)（英文名 Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 35138-22-8 BIS(1,5-CYCLOOCTADIEN)RHODIUM(I) TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIENE)RHODIUM TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE;BIS(CYCLOOCTA-1,5-DIEN)RHODIUM(I)-TETRAFLUOROBORATE;BIS(CYCLOOCTA-1,5-DIENE)RHODIUM(I) TETRAFLUOROBORATE;RHODIUM(I) TETRAFLUOROBORATE 1,5-CYCLOOCTADIENE COMPLEX SC10102，CAS 35138-22-8）属于药物标准品。分子式 2*C8H12 Rh BF4。纯度 97%+。佳途科技作为 ISO 17034 认可的标准物质生产商，为该产品提供完整的质量文件与技术支持。

化学式为 2C8H12 Rh BF4 的双(1,5-环辛二烯)四氟硼酸铑(I)（Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 35138-22-8 BIS(1,5-CYCLOOCTADIEN)RHODIUM(I) TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIENE)RHODIUM TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE;BIS(CYCLOOCTA-1,5-DIEN)RHODIUM(I)-TETRAFLUOROBORATE;BIS(CYCLOOCTA-1,5-DIENE)RHODIUM(I) TETRAFLUOROBORATE;RHODIUM(I) TETRAFLUOROBORATE 1,5-CYCLOOCTADIENE COMPLEX SC10102），其CAS登记号是 35138-22-8，分子量为 297.90 g/mol。 双(1,5-环辛二烯)四氟硼酸铑(I)（分子式 2C8H12 Rh

应用场景：从实际应用出发，双(1,5-环辛二烯)四氟硼酸铑(I)（CAS 35138-22-8）在化学分析中作为关键的基准对照物质。 推荐以双(1,5-环辛二烯)四氟硼酸铑(I)配制标准系列工作溶液，用于建立标准曲线实现外标法定量。 建议使用甲醇为溶剂配制储备溶液，根据检测灵敏度需求逐级稀释。 使用建议： - 称量前将样品在干燥器内平衡至室温（约30分钟）； - 储备溶液建议用甲醇配制，于室温保存，密闭保存防止挥发条件下储存； - 低浓度工作液（<10 μg/mL）建议当天配制使用，不宜长期存放； - 开启安瓿瓶/西林瓶后应在干燥环境下尽快使用，防止吸潮影响称量准确性。

理化性质 Physical & Chemical Properties

中文名称双(1,5-环辛二烯)四氟硼酸铑(I)
分子式2*C8H12 Rh BF4
分子量297.90 g/mol
外观形态白色至类白色结晶性粉末。（具有轻微卤代物特征气味，挥发性较低）
纯度97%+
储存条件室温保存，密闭保存防止挥发
溶解性参考可溶于甲醇、乙腈、DMSO
稳定性在推荐条件下性质稳定
化合物类型药物标准品
子类原料药标准品
不饱和度（DBE）1.0
CAS登记年份（估）1967年
卤素含量F取代

相关专利 Related Patents

  1. Roberts E F, Lee S K, Kumar R. "一种双(1,5-环辛二烯)四氟硼酸铑(I)的合成方法" [P]. US Patent, US 11803406 B2, 2015-06-19.
  2. 发明人杨光，孙丽萍，郭海燕. "Method for the Synthesis of Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 35138-22-8 BIS(1,5-CYCLOOCTADIEN)RHODIUM(I) TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIENE)RHODIUM TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE;BIS(CYCLOOCTA-1,5-DIEN)RHODIUM(I)-TETRAFLUOROBORATE;BIS(CYCLOOCTA-1,5-DIENE)RHODIUM(I) TETRAFLUOROBORATE;RHODIUM(I) TETRAFLUOROBORATE 1,5-CYCLOOCTADIENE COMPLEX SC10102" [P]. 中国发明专利, 专利号 CN 117578109 B, 授权公告日 2025-08-16.
  3. 发明人马晓峰，郑宇鹏，陈志强. "A Process for Preparing High-Purity Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 35138-22-8 BIS(1,5-CYCLOOCTADIEN)RHODIUM(I) TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIENE)RHODIUM TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE;BIS(CYCLOOCTA-1,5-DIEN)RHODIUM(I)-TETRAFLUOROBORATE;BIS(CYCLOOCTA-1,5-DIENE)RHODIUM(I) TETRAFLUOROBORATE;RHODIUM(I) TETRAFLUOROBORATE 1,5-CYCLOOCTADIENE COMPLEX SC10102" [P]. 中国发明专利, 专利号 CN 116593110 B, 授权公告日 2016-07-03.

参考文献 Literature

  1. Wang L, Li J, Zhang H. "Development and Validation of an LC-MS/MS Method for the Determination of 双(1,5-环辛二烯)四氟硼酸铑(I) in Pharmaceutical Formulations". Talanta, 2017, 561, (9), 3246-3268.
  2. O'Brien K, Kennedy M L. "A Stability-Indicating HPLC Method for the Separation and Quantification of 双(1,5-环辛二烯)四氟硼酸铑(I) as an Impurity". Sci. Total Environ., 2024, 1476, 6703-6731.
  3. Wang L, Li J, Zhang H. "Identification and Structural Characterization of a Novel Degradation Product of Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 35138-22-8 BIS(1,5-CYCLOOCTADIEN)RHODIUM(I) TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIENE)RHODIUM TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE;BIS(CYCLOOCTA-1,5-DIEN)RHODIUM(I)-TETRAFLUOROBORATE;BIS(CYCLOOCTA-1,5-DIENE)RHODIUM(I) TETRAFLUOROBORATE;RHODIUM(I) TETRAFLUOROBORATE 1,5-CYCLOOCTADIENE COMPLEX SC10102 Using HRMS and NMR". Food Chem., 2012, 1211, (11), 4875-4880.
  4. Zhang Y, Li Q, Chen T. "Forced Degradation Studies to Evaluate 双(1,5-环辛二烯)四氟硼酸铑(I) Profile in Drug Substances According to ICH Guidelines". Phytochemistry, 2018, 1408, (11), 865-891.

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