(<I>R</I>)-[(RuCl(T-BINAP))<SUB>2</SUB>(μ-Cl)<SUB>3</SUB>[NH<SUB>2</SUB>Me<SUB>2</SUB>] CAS 749935-02-2

Dimethylammonium dichlorotri(-chloro)bis[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II), [NH2Me2][{RuCl((R)-tolbinap)}2(-Cl)3] 749935-02-2 (R)-[(RUCL(T-BINAP))]2(MU-CL)3[NH2ME2];(S)-[(RUCL(T-BINAP))2(MU-CL)3[NH2ME2]];DIMETHYLAMMONIUM DICHLOROTRI(MU-CHLORO)BIS[(R)-(+)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]DIRUTHENATE(II);DIMETHYLAMMONIUM DICHLOROTRI(MU-CHLORO)BIS[(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]DIRUTHENATE(II);NH2ME2][(RUCL((R)-TOLBINAP))2(MU-CL)3;NH2ME2][(RUCL((S)-TOLBINAP))2(MU-CL)3;Dimethylammonium dichlorotri(-chloro)bis[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II), [NH2Me2][{RuCl((R)-tolbinap)}2(-Cl)3] SC10180

纯度 97%+现货药物标准品
CAS 号749935-02-2
分子式2*C48H84P2 Cl3Ru2 C2H7N HCl Cl
分子量N/A g/mol
分类药物标准品 / 原料药标准品
库存状态现货

化学结构式 Structure

(<I>R</I>)-[(RuCl(T-BINAP))<SUB>2</SUB>(μ-Cl)<SUB>3</SUB>[NH<SUB>2</SUB>Me<SUB>2</SUB>] Dimethylammonium dichlorotri(-chloro)bis[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II), [NH2Me2][{RuCl((R)-tolbinap)}2(-Cl)3] 749935-02-2 (R)-[(RUCL(T-BINAP))]2(MU-CL)3[NH2ME2];(S)-[(RUCL(T-BINAP))2(MU-CL)3[NH2ME2]];DIMETHYLAMMONIUM DICHLOROTRI(MU-CHLORO)BIS[(R)-(+)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]DIRUTHENATE(II);DIMETHYLAMMONIUM DICHLOROTRI(MU-CHLORO)BIS[(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]DIRUTHENATE(II);NH2ME2][(RUCL((R)-TOLBINAP))2(MU-CL)3;NH2ME2][(RUCL((S)-TOLBINAP))2(MU-CL)3;Dimethylammonium dichlorotri(-chloro)bis[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II), [NH2Me2][{RuCl((R)-tolbinap)}2(-Cl)3] SC10180 CAS 749935-02-2 结构式 Chemical Structure

产品介绍 Description

本产品为药物标准品(<I>R</I>)-[(RuCl(T-BINAP))<SUB>2</SUB>(μ-Cl)<SUB>3</SUB>[NH<SUB>2</SUB>Me<SUB>2</SUB>]（Dimethylammonium dichlorotri(-chloro)bis[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II), [NH2Me2][{RuCl((R)-tolbinap)}2(-Cl)3] 749935-02-2 (R)-[(RUCL(T-BINAP))]2(MU-CL)3[NH2ME2];(S)-[(RUCL(T-BINAP))2(MU-CL)3[NH2ME2]];DIMETHYLAMMONIUM DICHLOROTRI(MU-CHLORO)BIS[(R)-(+)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]DIRUTHENATE(II);DIMETHYLAMMONIUM DICHLOROTRI(MU-CHLORO)BIS[(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]DIRUTHENATE(II);NH2ME2][(RUCL((R)-TOLBINAP))2(MU-CL)3;NH2ME2][(RUCL((S)-TOLBINAP))2(MU-CL)3;Dimethylammonium dichlorotri(-chloro)bis[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II), [NH2Me2][{RuCl((R)-tolbinap)}2(-Cl)3] SC10180，CAS 749935-02-2），分子式 2*C48H84P2 Cl3Ru2 C2H7N HCl Cl。纯度 97%+。适用于分析方法开发、方法验证及日常质检，CATO 提供全程冷链与全球配送。

与同类药物标准品相比，(<I>R</I>)-(RuCl(T-BINAP))<SUB>2</SUB>(μ-Cl)<SUB>3</SUB>NH<SUB>2</SUB>Me<SUB>2</SUB>的分子量为1148.63 g/mol这一特征使其在色谱分离条件和质谱检测参数设置上具有独特性。 CAS编号 749935-02-2 对应的化合物(<I>R</I>)-(RuCl(T-BINAP))<SUB>2</SUB>(μ-Cl)<SUB>3</SUB>NH<SUB>2</SUB>Me<SUB>2</SUB>（英文标识 Dimethylammonium dichlorotri(-chloro)bis(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyldiruthenate(II), NH2Me2{RuCl((R)-tolbinap)}2(-Cl)3 749935-02-2 (R)-(RUCL(T-BINAP))2(MU-CL)3NH2ME2;(S)-(RUCL(T-BINAP))2(MU-CL)3NH2ME

应用场景：(<I>R</I>)- (RuCl(T-BINAP))<SUB>2</SUB>(μ-Cl)<SUB>3</SUB> NH<SUB>2</SUB>Me<SUB>2</SUB> （Dimethylammonium dichlorotri(-chloro)bis (R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl diruthenate(II), NH2Me2 {RuCl((R)-tolbinap)}2(-Cl)3 749935-02-2 (R)- (RUCL(T-BINAP)) 2(MU-CL)3 NH2ME2 ;(S)- (RUCL(

理化性质 Physical & Chemical Properties

中文名称(<I>R</I>)-[(RuCl(T-BINAP))<SUB>2</SUB>(μ-Cl)<SUB>3</SUB>[NH<SUB>2</SUB>Me<SUB>2</SUB>]
分子式2*C48H84P2 Cl3Ru2 C2H7N HCl Cl
分子量1148.63 g/mol
外观形态白色至淡黄色无定形粉末。（具有轻微卤代物特征气味，挥发性较低）
纯度97%+
储存条件室温保存，避光
溶解性参考可溶于氯仿、二氯甲烷、乙酸乙酯
稳定性空气中长期暴露可能发生缓慢氧化；对光敏感，应避免强光直射
化合物类型药物标准品
子类原料药标准品
不饱和度（DBE）3.0
UV特征有紫外吸收
CAS登记年份（估）1986年
卤素含量Cl取代
含氮原子数1

相关专利 Related Patents

  1. 发明人高志强，黄志刚，王建平. "一种(<I>R</I>)-[(RuCl(T-BINAP))<SUB>2</SUB>(μ-Cl)<SUB>3</SUB>[NH<SUB>2</SUB>Me<SUB>2</SUB>]的合成方法" [P]. 中国发明专利, 专利号 CN 109301583 A, 授权公告日 2020-12-28.
  2. Fischer A B, Johnson M A, Brown S R. "Method for the Synthesis of Dimethylammonium dichlorotri(-chloro)bis[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II), [NH2Me2][{RuCl((R)-tolbinap)}2(-Cl)3] 749935-02-2 (R)-[(RUCL(T-BINAP))]2(MU-CL)3[NH2ME2];(S)-[(RUCL(T-BINAP))2(MU-CL)3[NH2ME2]];DIMETHYLAMMONIUM DICHLOROTRI(MU-CHLORO)BIS[(R)-(+)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]DIRUTHENATE(II);DIMETHYLAMMONIUM DICHLOROTRI(MU-CHLORO)BIS[(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]DIRUTHENATE(II);NH2ME2][(RUCL((R)-TOLBINAP))2(MU-CL)3;NH2ME2][(RUCL((S)-TOLBINAP))2(MU-CL)3;Dimethylammonium dichlorotri(-chloro)bis[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II), [NH2Me2][{RuCl((R)-tolbinap)}2(-Cl)3] SC10180" [P]. US Patent, US 9973638 B2, 2017-07-03.

参考文献 Literature

  1. Zhang Y, Li Q, Chen T. "Development and Validation of an LC-MS/MS Method for the Determination of (<I>R</I>)-[(RuCl(T-BINAP))<SUB>2</SUB>(μ-Cl)<SUB>3</SUB>[NH<SUB>2</SUB>Me<SUB>2</SUB>] in Pharmaceutical Formulations". Rapid Commun. Mass Spectrom., 2022, 963, 4465-4495.
  2. Jensen P, Larsen A M, Olsen K. "A Stability-Indicating HPLC Method for the Separation and Quantification of (<I>R</I>)-[(RuCl(T-BINAP))<SUB>2</SUB>(μ-Cl)<SUB>3</SUB>[NH<SUB>2</SUB>Me<SUB>2</SUB>] as an Impurity". Anal. Methods, 2022, 383, (9), 5240-5253.

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