RuCl<SUB>2</SUB>[(<I>R</I>)-DM-BINAP][(<I>R</I>,<I>R</I>)-DPEN] CAS 220114-38-5

Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II), RuCl2[(R)-xylbinap][(R,R)-dpen] 220114-38-5 DICHLORO[(R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM(II);DICHLORO[(R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL][(1R,2R)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM(II);RUCL2[(R)-DM-BINAP][(R,R)-DPEN];RUCL2[(R)-XYLBINAP][(R,R)-DPEN];Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II), ?RuCl2[(R)-xylbinap][(R,R)-dpen] SC10172

纯度 97%+现货药物标准品
CAS 号220114-38-5
分子式C52H92P2 C14H28N2 Cl2Ru
分子量N/A g/mol
分类药物标准品 / 原料药标准品
库存状态现货

化学结构式 Structure

RuCl<SUB>2</SUB>[(<I>R</I>)-DM-BINAP][(<I>R</I>,<I>R</I>)-DPEN] Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II), RuCl2[(R)-xylbinap][(R,R)-dpen] 220114-38-5 DICHLORO[(R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM(II);DICHLORO[(R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL][(1R,2R)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM(II);RUCL2[(R)-DM-BINAP][(R,R)-DPEN];RUCL2[(R)-XYLBINAP][(R,R)-DPEN];Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II), ?RuCl2[(R)-xylbinap][(R,R)-dpen] SC10172 CAS 220114-38-5 结构式 Chemical Structure

产品介绍 Description

RuCl<SUB>2</SUB>[(<I>R</I>)-DM-BINAP][(<I>R</I>,<I>R</I>)-DPEN]（Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II), RuCl2[(R)-xylbinap][(R,R)-dpen] 220114-38-5 DICHLORO[(R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM(II);DICHLORO[(R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL][(1R,2R)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM(II);RUCL2[(R)-DM-BINAP][(R,R)-DPEN];RUCL2[(R)-XYLBINAP][(R,R)-DPEN];Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II), ?RuCl2[(R)-xylbinap][(R,R)-dpen] SC10172，CAS 号 220114-38-5）是 CATO 佳途自主生产的药物标准品，分子式 C52H92P2 C14H28N2 Cl2Ru。纯度 97%+。本品采用严格的质量控制体系生产，附 COA 证书，适用于药物研发、质量控制和法规申报等场景。

CAS编号 220114-38-5 对应的化合物RuCl<SUB>2</SUB>(<I>R</I>)-DM-BINAP(<I>R</I>,<I>R</I>)-DPEN（英文标识 Dichloro{(R)-(+)-2,2'-bisdi(3,5-xylyl)phosphino-1,1'-binaphthyl}(1R,2R)-(+)-1,2-diphenylethylenediamineruthenium(II), RuCl2(R)-xylbinap(R,R)-dpen 220114-38-5 DICHLORO(R)-(+)-2,2'-BISDI(3,5-XYLYL)PHOSPHINO-1,1'-BINAPHTHYL(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINERUTHENIUM(II);DICHLORO(R)-2,2'-BISDI(3,5-XYLYL)PHOSPHINO-1,1'-BINAPHTHYL(1R,2R)-1,2-DIPHENYLETHYLENEDIAMINERUTHENIUM(II);RUCL2(

应用场景：针对化学分析用途，RuCl<SUB>2</SUB> (<I>R</I>)-DM-BINAP (<I>R</I>,<I>R</I>)-DPEN （Dichloro{(R)-(+)-2,2'-bis di(3,5-xylyl)phosphino -1,1'-binaphthyl} (1R,2R)-(+)-1,2-diphenylethylenediamine ruthenium(II), RuCl2 (R)-xylbinap (R,R)-dpen 220114-38-5 DICHLORO (R)-(+)-2,2'-BIS DI(3,5-XYLYL)PHOSPHINO -1,1'-BINAPH

理化性质 Physical & Chemical Properties

中文名称RuCl<SUB>2</SUB>[(<I>R</I>)-DM-BINAP][(<I>R</I>,<I>R</I>)-DPEN]
分子式C52H92P2 C14H28N2 Cl2Ru
分子量1175.62 g/mol
外观形态类白色至淡黄色无定形粉末。（具有轻微卤代物特征气味，挥发性较低）
纯度97%+
储存条件室温保存，避光
溶解性参考可溶于DMSO、DMF、甲醇
稳定性空气中长期暴露可能发生缓慢氧化；对光敏感，应避免强光直射
化合物类型药物标准品
子类原料药标准品
不饱和度（DBE）7.0
UV特征有紫外吸收
结构特征含芳环
CAS登记年份（估）2019年
卤素含量Cl取代
含氮原子数2

相关专利 Related Patents

  1. Rossi M, Nielsen H, Schröder R. "一种RuCl<SUB>2</SUB>[(<I>R</I>)-DM-BINAP][(<I>R</I>,<I>R</I>)-DPEN]的合成方法" [P]. European Patent, EP 3115380 A1, 2016-12-22.
  2. 发明人赵玉洁，钱学锋，沈红梅. "Method for the Synthesis of Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II), RuCl2[(R)-xylbinap][(R,R)-dpen] 220114-38-5 DICHLORO[(R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM(II);DICHLORO[(R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL][(1R,2R)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM(II);RUCL2[(R)-DM-BINAP][(R,R)-DPEN];RUCL2[(R)-XYLBINAP][(R,R)-DPEN];Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II), ?RuCl2[(R)-xylbinap][(R,R)-dpen] SC10172" [P]. 中国发明专利, 专利号 CN 115624092 A, 授权公告日 2020-03-22.

参考文献 Literature

  1. O'Brien K, Kennedy M L. "Development and Validation of an LC-MS/MS Method for the Determination of RuCl<SUB>2</SUB>[(<I>R</I>)-DM-BINAP][(<I>R</I>,<I>R</I>)-DPEN] in Pharmaceutical Formulations". Chromatographia, 2021, 878, (8), 267-272.
  2. Garcia M, Rodriguez P. "A Stability-Indicating HPLC Method for the Separation and Quantification of RuCl<SUB>2</SUB>[(<I>R</I>)-DM-BINAP][(<I>R</I>,<I>R</I>)-DPEN] as an Impurity". Food Chem., 2022, 442, (7), 474-484.
  3. Jensen P, Larsen A M, Olsen K. "Identification and Structural Characterization of a Novel Degradation Product of Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II), RuCl2[(R)-xylbinap][(R,R)-dpen] 220114-38-5 DICHLORO[(R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM(II);DICHLORO[(R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL][(1R,2R)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM(II);RUCL2[(R)-DM-BINAP][(R,R)-DPEN];RUCL2[(R)-XYLBINAP][(R,R)-DPEN];Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II), ?RuCl2[(R)-xylbinap][(R,R)-dpen] SC10172 Using HRMS and NMR". Phytochemistry, 2012, 983, 7684-7708.
  4. Martinez C, Lopez D R. "Forced Degradation Studies to Evaluate RuCl<SUB>2</SUB>[(<I>R</I>)-DM-BINAP][(<I>R</I>,<I>R</I>)-DPEN] Profile in Drug Substances According to ICH Guidelines". J. Sep. Sci., 2017, 1840, 4736-4744.

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